Vitreous
silica is the generic term used to describe all types of silica
glass with producers referring to the material as either fused
quartz or as fused silica. Originally, these terms were used to
distinguish between transparent and opaque grades of the
material. Fused quartz products were those produced from quartz
crystal to make transparent ware, and fused silica described
products manufactured from sand into opaque ware.
Today,
however, advances in raw material beneficiation permit
transparent fusions from sand as well as from crystal.
Consequently if naturally occurring crystalline silica (sand or
rock) is melted, the material is simply called fused quartz.
When silicon dioxide is synthetically derived, however, the
material is referred to as synthetic fused silica.
Controlled
Process
The
performance of most fused quartz products is closely related to
the purity of the material. GE's proprietary raw material
beneficiation and fusion processes are closely monitored and
controlled to yield typically less than 50 ppm total elemental
impurities by weight. GE clear fused quartz varieties have a
nominal purity of 99.995 W% SiO2. The Table below
summarizes the typical trace level impurity content of GE fused
quartz products.
Structural
hydroxyl (OH)- impurities are also shown. The strong IR
absorption of (OH)- species in fused quartz provides a
quantitative method for analysis.
Beta
Factor
The
term Beta Factor is used to characterize the hydroxyl (OH)-
content of fused quartz tubing. This term is defined by the
formula shown below.
Beta
Factor = 
=
(1/t)log10 (Ta/Tb) mm-1
Where:
t = Quartz thickness, mm
Ta = actual % transmission at
= 2.6 µm
Tb = actual % transmission at
= 2.73 µm
[OH-]
= C, ppm
C =
× 910
910= (M.W.(OH)-× 104)/(E
×
(SiO2))
M.W.(OH)-= Molecular Weight of (OH)-g
= 17g
E = Extinction coefficient for (OH)-= 85
liters/mol-cm
=
Density of SiO2 = 2.21 g/cm3