Processing
begins by passing the ore through screens to sort and crush by
size. The ore is then fed to large grinding mills and mixed with
a caustic soda solution called liquor.
The shell of the grinding mill rotates, and steel rods rolling
around inside the shell grind the ore to an appropriate size.
The process is a lot like a kitchen blender only much slower and
much larger. The discharge from the mill is called slurry.
The
slurry is pumped to a digester where the chemical reaction to
dissolve the alumina takes place. In the digester the slurry is
heated to 300 degrees Fahrenheit or 145 degrees Celsius (all
while being under 50 pounds per square inch pressure) and it
stays in those conditions for 30 minutes to several hours.
More
caustic soda is added at this point, in order to dissolve
aluminum containing compounds in the slurry. Undesirable
compounds either don't dissolve in the caustic soda, or combine
with other compounds to create a scale on equipment which must
be periodically cleaned. The digestion process produces a
sodium aluminate solution.
Because
all of this takes place in a pressure cooker, the slurry is
pumped into a series of flash tanks to reduce the pressure and
recover heat before moving on to the settling tanks.
From
the flash tanks, the slurry travels to settling tanks. Most of
the work here is handled by simple gravity, although some
chemicals are added to help the settling process.
Just
as a glass of sugar water with fine sand suspended in it will
separate out over time, the impurities in the slurry -- things
like sand and iron and other trace elements that do not dissolve
-- settle to the bottom.
The
liquor at the top of the tank, which looks like coffee at this
point, then moves on to a series of filters. The remaining red
mud is pumped off and, after washing to recover alumina and
caustic soda, is sent to dry out in large storage ponds.
The
alumina left in the liquid moving along in the process now
consists of tiny crystals suspended in a liquor that's still quite
warm at this point, however there are still some very fine solid
impurities that must be removed. Just as coffee filters keep the
grounds out of your cup, the filters here work the same way.
The
giant-sized filters consist of a series of "leaves" --
big cloth filters over steel frames and remove much of the
remaining solids in the liquor. The material caught by the
filters is known as a filter cake and is washed to remove
alumina and caustic.
The
filtered liquor is then cooled and pumped to the precipitation
process.
Imagine
a tank as tall as a six-story building. Now imagine row after
row of those tanks. And imagine that those tanks are filled with
millions of tiny particles of alumina.
Seed
crystals -- alumina hydrate-- are poured into the top of these
tanks called precipitation, which helps the alumina crystals
grow bigger and settle to the bottom. The crystals pulled from
the bottom of the tank move along to thickening tanks, and from
there to filters and calcination kilns.
Calcination
is a heating process to remove the chemically combined water
from the alumina hydrate.
That's
why, once the hydrated alumina is calcined, it's known as
anhydrous alumina. "Anhydrous" means "without
water."
From
precipitation, the hydrate is filtered and washed to rinse away
impurities and remove moisture. A continuous screw conveyor
moves the hydrate into the calcining kiln.
The
calcining kiln is brick-lined inside and gas-fired to a
temperature of 2,000 degrees Fahrenheit or 1,100 degrees
Celsius. It slowly rotates (to make sure the alumina dries
evenly) and is set upon a tilted foundation which allows the
alumina to make it's way to the cooling equipment, shown at the
right . (Newer plants use a method called fluid bed calcining
where alumina particles are held in suspension by hot air and
calcined.)
At
this point, the alumina is ready for conversion into aluminum at
a smelter. Alumina can also be used in chemical and ceramic
applications.
In
1886, two 22-year-old scientists on opposite sides of the
Atlantic, Charles Hall of the USA and Paul L.T. Heroult of
France, made the same discovery -- molten cryolite (a sodium
aluminum fluoride mineral) could be used to dissolve alumina in
order to produce metallic aluminum. The Hall-Heroult process
remains in use today.
The
key to the chemical reaction was the running of an electrical
current through the cryolite/alumina mixture.
It
has to be direct current -- not the alternating current used in
homes -- and it is the reason why the location of aluminum
plants is based in large part on the availability of affordable
electrical power. Some experts believe one percent of all the
energy used in the United States is used in the making of
aluminum.
The
Hall-Heroult process takes place in an electrolytic cell called
a reduction pot. The current used in a typical reduction pot is
only 5.25 volts, but the amperage generally tops 100,000
amperes.
The
steel tubs are lined with carbon, and the carbon acts as one
pole or carbon electrode (called the cathode). The other
electrode (called the anode) is dipped into the molten mix of
cryolite and alumina from above.
When
the electric current passes through the mixture, the carbon of
the anode combines with the oxygen in the alumina and drifts
away as carbon dioxide. The metallic aluminum settles to the
bottom of the pot, where it is periodically syphoned off into
crucibles. From here the metal can be forged, turned into
alloys, or extruded into the shapes and forms of which you are
familiar.
Very
little cryolite is ever lost in the process, and the alumina is
constantly replenished from storage containers above the
reduction pots. In most plants, reduction pots are lined up in
long rows, called potlines, and are usually kept in production
24 hours a day year-round.