Talc

Hydrated Magnesium Silicate
3MgO.4SiO₂H₂O

Talc is one of the most important industrial minerals and is the most common mineral for daily use as a body and face powder.

The History Says

Talc, a word derived form the greek word talq meaning pure, is a unique mineral.

The Present Scenario

There are important deposits of talc in Austria, Italy, France, and Canada and in the United States in California, North Carolina, Texas, Georgia, and Montana. Talc is used in making paper (as a filler), paints, face and talcum powder, soap, fireproof roofing, foundry facings, lubricants, linoleum and oilcloth, electrical insulation, and pottery.

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TALC is also written as H₂Mg₃(SiO₃)₄, which corresponds to 4.8% H₂O; 31.7% MgO and 63.5% SiO₂. It is essentially a secondary mineral formed by the hydrothermal actions and regional metamorphism of magnesium rich rocks like dolomite, pyroxenite, amphibolite, seerpentine, dunite and chlorite.

In pulverized form it is whiter in appearance. The compact variety of talc is called steatite or soapstone. The word soapstone has been named probably due to its soapy feel. The impure and hard variety is called potstone, which is mainly utilized for making carvings, models, decorative vases, utensils, pots and the like and hence the name potstone.

French-chalk is the trade name of pulverized talc of pure white quality which forms the base for many cosmetics and toilet preparations. Talc is valued for its extreme softness, smoothness, high lubricating and hiding power and ability to absorb oil and grease. It is chemically inert to acids and alkalies.

It has been found to be an excellent filler. It can withstand temperatures upto 1300ºC. It has low electrical and thermal conductivity. Above all it can be easily powdered, cut and sawn into any shape and size. These properties in talc are of extreme value for various industrial applications described later in this chapter.

Talc is found in three forms, fibrous, nonfibrous and massive. The fibrous variety consists of rich proportions of tremolite, anthophyllite, and serpentine. The nonfibrous variety contains mostly of srpentine and carbonates. Fibrous variety is slightly difficult to grind.

Hardness	Synonym	Chemical/Typical composition	Colour	characteristics	Luster	Streak
1	Kerolite Magnesium Talc Soapstone Steatite-massive	MgO 31.88 % SiO2 63.37 % H2O 4.75 %	Silvery Green Grey white	Has a soapy feel to the touch	Dull to pearly or greasy	white

Models and Occurance

It occurs usually intimately associated with magnesium-rich minerals. Anthophyllite, termolite, diopside, dolomite, sometimes quartz and calcite are the common minerals found in association with talc. It is found as soft mass in the forms of bands, lenses and vein-like bodies enclosed in dolomite country rock. Veins vary from small in dimensions to very large, usually 25-40 metres long and 12-18 metres wide. It has been mined up to a depth of 20 metres. Lenses of soapstone are separated by dolomite and also dolomite is found enclosed within the soapstone mass. It is of compact variety.

Classification and Preparation for the Market

Talc is classified according to its colour (colour of the powder) and softness. There is no standard basis of classifying it. The whiter variety is preferred to dull and other tinted varieties.

Talc is mostly used in pulverized form. About 90% of the world's production is pulverized for various applications and the remaining 10% is used in the form of bricks and blocks. Suitable lumps are picked up from the run-of-mine for making into blocks and cut into different sizes with the help of knives. Other materials are sold to pulverizers for resale to consumers. Talc is pulverized to varying fineness, from 200 mesh to 325 mesh. For the preparation of cosmetics, talc of over 300 mesh is required. The fine mesh sizes of 200 and over are prepared for use as filler in paper, rubber and textile depending upon the fineness required by the consumers. Market specifications are dependent upon the colour, fineness, chemical composition, oil absorption property and bulk density.

Industrial Applications

Talc is one of the most important industrial minerals and is the most common mineral for daily use as a body and face powder. Talcum Powder, the name derived from the mineral itself, is used in most urban homes the world over. The invention of perfumed talcum powder has been a contributing factor in the growth of modern fashions in cosmetics. The use of talc was known to civilisations in antiquity. The ancient craftsmen of the Mohenjodaro and Harappa civilisation, (in Sind, now in Pakistan), about 5000 years ago, exercised their skill on steatite, engraving their seals with representations of animals and mythological signs, before subjecting the carving to heat to acquire hard, white lustrous, enamelled surfaces. Small sculptures, ornate bosses and vessels were also made from the mineral during those early times.

Pulverized talc has wide industrial applications as filler in rubber, textile, plastic, linoleum, asbestos products, polishes and soaps; as a loading agent for paper of all kinds; as a carrier of insecticidal and pesticidal dusts and for coating calcium ammonium fertiliser. Most of the rubber manufacturers use talc powder as a lubricant to prevent ungalvanized rubber goods from sticking. The purer variety of steatite after calcination, industrially called 'Lava' is used in the manufacture of low loss ceramic materials required for high frequency insulations in all kinds of radio, television and related instruments. Bricks made out of crushed steatite bonded by sodium silicate are used for ssthe manufacture of furnaces in which argentiferous lead is softened before desilverising. Paper industry accounts for about 50% of the total consumption, in the domestic industry, 15% is shared by the insecticide and pesticide industries and only 3% by talcum powder manufacturers. The remaining quantity is consumed in textile, ceramics, paints, rubber, foundry facing and other industries.

Paper
Talc both in pulverized and brick forms, are used in this industry. Pulverized material of 200-300 BSS sieve is required as filler. It is used in the same way as china clay, that is, the talc powder is mixed with pulp before making into paper. A number of paper manufacturers are changing over from the use of china clay to French chalk as filler and loading material. The brightness in talc is 85 to 88º as compared to 75º in china clay. Since 1960, the consumption of talc in the paper industry has greatly increased. Paper industry requires talc powder, known as French chalk, of pure white quality. It should be free from gritty material. It should have low CaCO₃ content, not exceeding 4%; also FeO should not be more stha 2%. Off-colour variety of talc free from grit is used for brown, roofing or inferior type of paper. Soapstone bricks are used for lining pulp tanks in the paper industry.

Textiles
Textile industry also prefers talc powder free from grit and colouration, which is used both for loading and bleaching certain types of cotton goods. Inferior grades are used in back filling textiles.

Cosmetics
In the manufacture of body and face powder, finely pulverized talc of very high purity is required. The material is generally reduced to fine particles by micronising. Cosmetics are prepared with a base of talc to which are added covering agents like pigments and adhesives, starches and perfumes. A common adhesive is zinc stearate. It is now being fast substituted by lithium stearate. In the manufacture of dentrifices some quantity of talc is used, here as a polishing agent. Dentrifices are prepared by mixing suitable proportions of polishing agents like talc, precipitated limestone, kaolin, calcium sulphate, calcium phosphate with gum, glycerin, soap and other chemical ingredients.

The pharmaceutical industry requires talc containing less than 0.1% FeO. Natural material of such purity is generally not found and pharmaceutical talc is preferred by passing the high purity powdered talc over a magnetic separator to reduce the iron content.

Rubber
In rubber industry talc is used for two purposes, one to prevent rubber moulds from sticking and the other as compunding material in the preparation of certain types of hard rubber. The consumption of talc for the latter use is small. Generally grade II to III are used in the rubber industry. Talc should be of fine mesh all passing through 200 mesh.

Ceramics
Talc is increasingly being used in the manufacture of artwares, jars, wall and floor tiles. It serves as a non-plastic ceramic material. The addition of talc in suitable proportions in the body of mixtures for porcelain, jars etc. prevents the crazing (cracking) effect on the glazes. The proportion of talc in the ceramic body may go upto 80%. It is valued for its refractoriness and stability, as well as extremely low shrinkage at high temperature. Talc converts into clino-enstatite at about 1300º C. Between 800ºC to 840ºC, the water molecules are driven off and talc dissociates into enstatite and amorphous silica without undergoing any change in shape, the shrinkage being 0.0005 inch only.

In the manufacture of ceramic goods required for the electrical industry, the talc should not contain more than 1.5% FeO and CaO. Some consumers do not regard CaO as having any harmful effect.

Steatite suitable for the manufacture of 'lava' insulators must he dense, compact, uniform and homogeneous intexture, free from any inclusion and parting planes. It should not contain CaO more than 1.5% and Fe₂O₃; more than 1%. The iron oxide is a colourant and gives the fired shapes an unattractive colour. An increase of iron oxide above two per cent decreases the 'Q' value (ratio of reactance to resistance) and increases the dielectric constant. CaO imparts abrasiveness and usually a short vitrification range and sometimes a high firing shrinkage.

Paints
In this industry, foliated, fibrous or lamellar talc of fine mesh (300 mesh) is preferred. It is used as a paint or an extender in paint industry. Colour, particle size and oil absorption are the main criteria for selecting talc for paint manufacture. Talc suitability for paint should have volatile matter below 0.75%, oil absorption within 5 of the approved sample and solubility not more than 0.25% in water. Asbestine is the trade name given to fibrous talc suitable for paint making.

Other uses
A fair proportion of medium to inferior grades of talc is used in the manufacture of perticides and insecticides. Talc is used here as a carrier. Talc powder prevents infestation of food grains from insectsand pests and hence it is sprinkled over food grains kept in big godowns. Other uses are for making crayons for marking purposes and for tailors' chalk.

World Resources

Talc is mined in many countries. Some of the finest grades of cosmetic and pharmaceutical talc are obtained from the Pyrenees in France and the Alps in Italy. In Europe, Austria, France, Italy, and Norway are the important producers and exporters. Canada is a small producer with an average production of 23,000 tonnes annually from Ontario and Quebec. A small production of talc is reported from five provinces of Brazil, namely, Bahia, Mines Gerais, Parna, Rio de Janeiro and Sao Paulo. Production from the Republic of Korea and Brazil is of the same order as that of Canada. African countries are also small producers. Production of talc in China and USSR is reported to be 150,000 tonnes and 300,000 tonnes per annum respectively.