Sodium
Sulfate
Na2SO4
SODIUM
SULFATE IS one of the most important minerals in the chemicals
industry. It is an important compound of sodium. It is a white
crystalline solid when anhydrous. The decahydrate (Na2SO4.10H2O)
is known as Glauber's salt.
Synonyms of Sodium Sulfate
- Disodium
monosulfate
- Sulfuric
acid, Sodium salt
- Disodium
sulfate
- Sulfuric
acid, Disodium salt
- Bisodium
sulfate
- Natriumsulfat
-
Salt cake
- Thenardite
(mineral)
- Glauber's
salt (decahydrate)
- Sal
mirabilis (decahydrate)
- Mirabilite
(decahydrate)
- Trona
Physical Properties of Sodium Sulfate
| Physical state |
Hygroscopic white
powder, Odorless |
| Density |
2.68 g/cm3, anhydrous
(orthorhombic form) 1.464 g/cm3, decahydrate |
| Solubility in water |
4.76 g/100 ml (0°C)
42.7 g/100 ml (100°C) |
| Solubility in ethanol |
Insoluble |
| Boiling point |
1100°C (Decomposes) |
| Melting point |
884°C (1157 K) anhydrous
32.4°C decahydrate |
| Specific gravity |
2.66 - 2.75 |
Uses of Sodium Sulfate
- To
make soaps and detergents. It is an important ingredient in powdered
soaps.
- To
make textiles.
- In
the production of paper and paper pulp and glass.
Substitutes of Sodium Sulfate
Emulsified sulfur and sodium hydroxide (caustic soda) is sometimes
used in place of sodium sulfate in paper production. In soap and
detergent production also it is easily replaced by a number of
products. In glass production, it is replaced by soda ash and calcium
sulfate. The glass produced by the substitute is considered "less-than-perfect."
Sources of Sodium Sulfate
Approximately 12% of the salt in the Great Salt Lake of Utah is
Sodium sulfate. This is equivalent to 400 million tons of sodium
sulfate. Nevada, Washington and Wyoming in the United States also have
identified sodium sulfate resources.
Apart from the US, deposits are also found in Canada, Mexico, Spain,
Turkey, China, Egypt, Italy, Romania and South Africa.
Significant amount of sodium sulfate are also produced as a
by-product from the production of other materials, like ascorbic acid,
boric acid, cellulose, rayon, and silica pigments.
In paper and paper pulp industry, a small amount is recycled.
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