Bauxite
Mixture
of Iron and Aluminium Hydroxides/Oxides
Al, Fe, O, OH
Bauxite does not require complex processing because most of the
bauxite mined is of an acceptable grade or can be improved by a
relatively simple and inexpensive process of removing clay.
The History Says
The first aluminum made in the US. was mined in Bartow and Floyd
counties by the present Aluminum Company of America. A local man, Mr.
Gibbons, operated these mines and also deposits in Arkansas, where the
town near the deposits was named for him. He became a top official of
Alcoa. The American Cyanamid Company mined bauxite to make alum. Large
foreign deposits caused local mining to cease.
The Present Scenario
Exporting bauxite mines generated about US$1.4m in revenue per
hectare mined in 1998 and a typical mine employed about 200 people for
each million tonnes/year of bauxite produced or about 11 people per
hectare.
BAUXITE
is a naturally occurring, heterogeneous material composed primarily of
one or more aluminum hydroxide minerals, plus various mixtures of
silica, iron oxide, titania, aluminosilicate, and other impurities in
minor or trace amounts. The principal aluminum hydroxide minerals
found in varying proportions with bauxites are gibbsite and the
polymorphs boehmite and diaspore. Bauxites are typically classified
according to their intended commercial application: abrasive, cement,
chemical, metallurgical, refractory, etc. The bulk of world bauxite
production (approximately 85%) is used as feed for the manufacture of
alumina via a wet chemical caustic leach method commonly known as the
Bayer process. Subsequently, the majority of the resulting alumina
produced from this refining process is in turn employed as the
feedstock for the production of aluminum metal by the electrolytic
reduction of alumina in a molten bath of natural or synthetic cryolite
(Na3AlF6), the Hall-Héroult process.
Formula
Al2O3 + SiO2 + TiO2 +
Fe2O3
Typical Chemical Properties Available
Purities available from 98% (industrial grade) to 99.999% (high
purity grade).
Typical Physical Properties Available
Physical properties vary widely according to the mine source.
Granulations available include: 50 mm by down lumps, crushed coarse
sizes (-3 mesh, -6 mesh, -8 mesh and -12 mesh) and ground powder sizes
(-100 mesh, -200 mesh and -325 mesh).
Nominal Physical Constants:
| Molecular Weight (g/mol.) |
- |
| Apparent Density (g/cm3) |
3.08 |
| Bulk Density (g/cm3) |
3.1 |
| Calcination Temperature(°C)
|
1650 |
| Boiling Point (°C) |
- |
| Specific Surface Area (m2/g)
|
- |
| Thermal Conductivity (cal/s-cm-°C)
|
- |
| Mohs Hardness @20°C |
- |
| Specific Gravity |
2.45- 3.25 |
| Apparent Porosity (%) |
8.4 |
| L.O.I. (%) |
0.1 |
Bauxite
Mining in Forest Areas
The conservation of rain forests is a key concern often voiced with
regard to bauxite mining. Only about 6 % of the world's bauxite mining
is today conducted in rain forest regions, affecting a total area of
around 1.5 km2 per year. The total area of the globe currently covered
by rain forest is about 18 million km2. The original flora and fauna
of much of the land involved in bauxite mining is restored once mining
operations have ceased. For all forest areas used for bauxite mining,
80% is returned to native forests, the rest is replaced by
agriculture, commercial forest, or recreational area, thereby making
the area more productive for the local community. As far as rain
forests in particular are concerned, however, the area used for
bauxite mining in rain forests is almost totally reverted back to rain
forest.
Bauxite mining
There are numerous bauxite deposits, mainly in the tropical and
subtropical regions, but also in Europe. Bauxite is generally
extracted by open cast mining from strata, typically some 4-6 metres
thick under a shallow covering of topsoil and vegetation. In most
cases the topsoil is removed and stored.
Exporting bauxite mines generated about US$1.4m in revenue per
hectare mined in 1998 and a typical mine employed about 200 people for
each million tonnes/year of bauxite produced or about 11 people per
hectare. Usually mines offer relatively well-paid jobs and mining
companies tend to provide assistance to their neighbouring
communities.
There are attractive commercial and social reasons for the
development of a bauxite mine. The mining company wants the ore to use
or sell while the local inhabitants want the mine for employment and
for the community assistance that the mining company usually offers.
National governments want the development for these social reasons and
also for the revenue provided by a mining company.
These social benefits are complemented, according to the
International Aluminium Institute's latest "Bauxite Mine
Rehabilitation Survey", by the mining companies' increasing
awareness of environmental factors. Mined areas are being restored to
an environmentally stable condition: 92.7% of surveyed operations have
formal, written rehabilitation procedures in place. A total of 282km2
(28,245 ha) of land has been rehabilitated to date at 22 operations.
Our survey shows that increasingly mining companies are concerned
about environmental matters. Bauxite mining is accompanied by land
rehabilitation and environmental control to restore the area to a
desirable environmentally friendly condition. It is possible for
everyone to gain from mining activities.
Bauxite mining method
Eighty percent of world bauxite production, mainly from large blanket
type deposits is from surface mines, with the rest, mainly from
Southern Europe and Hungary, from underground excavations. On some
surface deposits there is no overburden, and on others, the bauxite
may be covered by 70 metres or more of rock and clay. Deposits that
are hardened may require blasting in order to release the ore. Once
the bauxite is loosened into manageable pieces it is generally loaded
into trucks or railroad cars and transported to crushing or washing
plants or to stockpiles. Underground bauxite mines are used to exploit
pockets or beds of deposit between layers of carbonic rock. Water in
flow is a problem in most underground operations and dewatering shafts
are often drilled before mining begins.
Unlike the base metal ores, bauxite does not require complex
processing because most of the bauxite mined is of an acceptable grade
or can be improved by a relatively simple and inexpensive process of
removing clay. In many bauxites, clay is removed by some combination
of washing, wet screening and cycloning, even by hand picking or
sorting.
Traditional uses of bauxite
- Blast
Furnaces
- Iron/Steel
Ladles
- Torpedo
Cars
- Electric
Arc furnaces
- Tundishes
- Soaking
Pits
- Reheat/Soaking
Pits
- Open
Hearth
- Cement
- Aluminum
World
Bauxite Mine Production, Reserves, and Reserve Base
(x1000 tonne)
Mine production Reserves Reserve base
2000 2001
| Australia |
53,800 |
53,500 |
3,800,000 |
7,400,000 |
| Brazil |
14,000 |
14,000 |
3,900,000 |
4,900,000 |
| China |
9,000 |
9,200 |
720,000 |
2,000,000 |
| Guinea |
15,000 |
15,000 |
7,400,000 |
8,600,000 |
| Guyana |
2,400 |
2,000 |
700,000 |
900,000 |
| India |
7,370 |
8,000 |
770,000 |
1,400,000 |
| Jamaica |
11,100 |
13,000 |
2,000,000 |
2,500,000 |
| Russia |
4,200 |
4,000 |
200,000 |
250,000 |
| Suriname |
3,610 |
4,000 |
580,000 |
600,000 |
| United States |
NA |
NA |
20,000 |
40,000 |
| Venezuela |
4,200 |
4,400 |
320,000 |
350,000 |
| Other countries |
10,800 |
10,200 |
4,100,000 |
4,700,000 |
| World total (rounded) |
135,000 |
137,000 |
24,000,000 |
34,000,000 |
The Major Producers
China
Today, exportable refractory-grade bauxite (essentially all
diasporitic) is mined mainly from two provinces in China-Shanxi and
Guizhou. Shanxi reportedly exports two-thirds of the total.
The Guizhou and Shanxi materials have similar characteristics,
however, Guizhou has the disadvantage of higher TiO2 (3.7% typical vs.
4.2) and alkalies (0.2% typical vs. 0.6).
Although there have been unconfirmed reports of higher bulk densities
in Guizhou, the two provinces are essentially the same in principle,
with Shanxi possibly having the edge. In this case, chemistry is a
minor influencing factor (lower alkali content, higher Al2O3 in
Southern Shanxi), meaning bulk densities in China are primarily a
function of the calcining equipment and process.
With residence time as a primary factor, their minimum control
rudimentary shaft kilns are limited to maximum range BSGs (3.20-3.25).
Rotary kilns can produce up to the 3.30 range and the Chinese round
kilns can produce up to 3.35 by means of a special 18th century
burning procedure.
It is estimated that 50% of Chinese refractory-grade bauxite is
produced in updraft shaft kilns, with the remainder split between
round and rotary.
The Chinese bauxite supply picture is complicated because there are
~300 bauxite mines in China, with the exported product rarely
representing a single mine source. When ISO-9000 comes to
refractory-grade bauxite in China, it will be with some difficulty.
The supply of Chinese refractory-grade bauxite has improved during
the past 20 years-in part due to the installation of several
controlled processing plants in Tianjin. However, the basic supply
from the mine to the kiln to the port still involves considerable
rudimentary control and consequent quality variations. This could
improve significantly if experienced third parties get involved in the
mining and calcining of the material.
Despite numerous complaints that the Chinese producers have been
dumping, it does not appear to be probable. In any case, recent export
and provincial taxes will now force the Chinese prices somewhat closer
to world market levels. This will tend to promote a switch back to
South American bauxites.
Refractory-grade bauxite also is used to produce brown-fused alumina,
a significant product in China. Total current production there is
reportedly in excess of 300,000 tpy.
Brazil
The MSL Minerais (CAEMI) operation is the new supplier on the block.
Despite some apparent built-in disadvantages, it has managed to
develop a niche market and justify the installation of a second rotary
kiln in 1994. Thus, increasing total productive capacity to ~140,000
tpy.
Although the bauxite vein at CAEMI is only 1-3 m thick, the
relatively 8-12 m thick overburden is within an acceptable proportion.
Therefore, mining costs should be relatively low. The crude ore must
be beneficiated, first by crushing (10 mm maximum) washing and
screening, then with a heavy media process to remove iron. After
calcining, the material goes through eight iron-removing magnetic
separators. Despite the relatively high SiO2 content (approaching
10%), the beneficiation costs and relatively higher fuel costs for
calcining, the finished product is priced lower than Guyana RASC, and
has gained significant market share-particularly in Europe.
The higher SiO2 and lower alkalies in the MSL bauxite, together with
a uniform fine kiln feed size, contributes to the higher level of
mullite (and lower corundum) in the final product. TiO2 is a low 2.2%,
tielite a low 0-2%.
Guyana
Bauxite was first identified in Guyana in the period 1897-1910.
Although Alcoa Industrial Chemicals began alumina-grade bauxite
production in Guyana in 1917, and Alcan took over in 1929, it was not
until 1938 that refractory-grade bauxite was separately identified and
produced. The typical processing of Guyanese bauxite is
straightforward: Bauxite is crushed to -9 cm, washed and screened,
crushed to -4 cm, rewashed, then rotary kiln calcined, with some final
de-ironing before shipment.
Refractory-grade bauxite from Guyana presently falls into two
separate geographic sourcings: the original Linmines' home of the
traditional world standard RASC bauxite; and the Berbice/Bermine
operation, the latter primarily a source of abrasive- and
chemical-grade bauxite.
Reserves at Linmines are substantial. Ongoing improvements to
operating practices and costs began five years ago, with the
consequent gradual improvement to a global competitive marketing
position.
A privatization program now in progress in Guyana should contribute
to an improved bauxite product, availability and costs.
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